Chemistry Letters p. 185 - 188 (1990)
Update date:2022-08-11
Topics:
Ikenaga, Kazutoshi
Matsumoto, Satoshi
Kikukawa, Kiyoshi
Matsuda, Tsutomu
Both β-(E)- and β-(Z)-styryltrimethylgermanes easily reacted with arenediazonium tetrafluoroborates under palladium catalysis to give aryldegermylated products, (E)-PhCH=CHAr and Ph(Ar)C=CH2.On the other hand, the aryldegermylation of α-styrylgermane gave (E)-stilbene derivates with high stereo- and regioselectivities.
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