Journal of Organic Chemistry p. 2280 - 2282 (1991)
Update date:2022-08-24
Topics:
Hacker, Nigel P.
Leff, Daniel V.
Dektar, John L.
Diphenyliodonium halides exist as tight ion pairs in acetonitrile, and photolysis gives almost exclusively iodobenzene by a homolytic cleavage reaction from a charge transfer excited state, whereas in aqueous acetonitrile the ion pairs are solvent separated and photolysis gives substantial amounts of 2-, 3-, and 4-iodobiphenyls, in addition to iodobenzene, by an initial heterolytic cleavage.
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