Journal of Physical Chemistry p. 4644 - 4648 (1988)
Update date:2022-08-28
Topics:
Martinez, Richard I.
Herron, John T.
The reaction of ozone with trans-2-butene has been studied in the gas phase at 294 K and 530 Pa (4 Torr) by using a stopped-flow reactor coupled to a photoionization mass spectrometer.The concentrations of reactants and products were determined as a function of reaction time.A mechanism is proposed to account for the observed products: CH3CHO, H2CO, CO2, CH4, CF3C(O)C(H)(OH)CH3, H2C=C=O, H2O, 2-butanone, 2,3-epoxybutane, CH3C(O)C(O)CH3, and HC(O)C(O)H.This work again indicates that simple "hot" ester hypothesis needs to be critically reconsidered for gas-phase ozonolysis.
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