Copper(II) exchanged cation exchange resin: Useful activator in the reduction of ketones

Article abstract of DOI:10.1080/00397919308009781

A copper(II) exchanged cation exchange resin has been used as support for reduction of ketones with sodium borohydride. Supported Cu(II) ions activate the reduction of ketones to a large extent and control the stereochemistry of reductions of cyclic ketones resulting in preponderance of equatorial alcohol in most cases.

Full text of DOI:10.1080/00397919308009781

This article was downloaded by: [North Carolina State University]
On: 17 October 2014, At: 04:56
Publisher: Taylor & Francis
Informa Ltd Registered in England and Wales Registered Number: 1072954
Registered office: Mortimer House, 37-41 Mortimer Street, London W1T 3JH,
UK
Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
Publication details, including instructions for
authors and subscription information:
http://www.tandfonline.com/loi/lsyc20
Copper(II) Exchanged Cation
Exchange Resin: Useful
Activator in the Reduction of
Ketones
a
a b
a
A. Sarkar , B. R. Rao
& B. Ram
a
Department of Applied Chemistry , Indian School
of Mines , Dhanbad, 826004, INDIA
b
R. R. Lab. , Bhopal, 462026, India
Published online: 23 Sep 2006.
To cite this article: A. Sarkar , B. R. Rao & B. Ram (1993) Copper(II) Exchanged
Cation Exchange Resin: Useful Activator in the Reduction of Ketones, Synthetic
Communications: An International Journal for Rapid Communication of Synthetic
Organic Chemistry, 23:3, 291-296, DOI: 10.1080/00397919308009781
To link to this article: http://dx.doi.org/10.1080/00397919308009781
PLEASE SCROLL DOWN FOR ARTICLE
Taylor & Francis makes every effort to ensure the accuracy of all the
information (the “Content”) contained in the publications on our platform.
However, Taylor & Francis, our agents, and our licensors make no
representations or warranties whatsoever as to the accuracy, completeness,
or suitability for any purpose of the Content. Any opinions and views
expressed in this publication are the opinions and views of the authors, and
are not the views of or endorsed by Taylor & Francis. The accuracy of the

Content should not be relied upon and should be independently verified with
primary sources of information. Taylor and Francis shall not be liable for any
losses, actions, claims, proceedings, demands, costs, expenses, damages,
and other liabilities whatsoever or howsoever caused arising directly or
indirectly in connection with, in relation to or arising out of the use of the
Content.
This article may be used for research, teaching, and private study purposes.
Any substantial or systematic reproduction, redistribution, reselling, loan,
sub-licensing, systematic supply, or distribution in any form to anyone is
expressly forbidden. Terms & Conditions of access and use can be found at
http://www.tandfonline.com/page/terms-and-conditions