threo-Selective Synthesis of β-Methylhomoallyl Alcohols via But-2-enyltitanium Compounds

DOI: 10.1039/c39810001140

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1140 - 1141 (1981)

Update date:2022-08-29

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Authors:

Sato, Fumie

Iida, Katsumi

Iijima, Satoshi

Moriya, Hiroyuki

Sato, Masao

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Article abstract of DOI:10.1039/c39810001140

The diastereoselectivity of the addition of but-2-enyltitanium compounds, (η⁵-C5H5)2Ti(CH2CH=CHMe)X, to aldehydes is highly dependent on the halide ligand X, and high threo-selectivity is attained when X is Br or I.

Full text of DOI:10.1039/c39810001140

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