CYCLIZATION OF UNSATURATED ALDEHYDES CATALYZED BY (PPh3)2Co(Ph2PCH2CH2PPh2)

DOI: 10.1007/BF01168087

Source and publish data:

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 2353 - 2356 (1989)

Update date:2022-08-11

Topics:

Authors:

Vinogradov, M. G.

Tuzikov, A. B.

Nikishin, G. I.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1007/BF01168087

Catalytic cyclization of γ,δ-unsaturated aldehydes (intramolecular hydroacylation) in the presence of (PPh3)2Co(Ph2PCH2CH2PPh2) gives four-membered and five-membered cycloalkanones.Depending on aldehyde structure the selectivity is 90-97percent at 10-100percent aldehyde conversion.

Full text of DOI:10.1007/BF01168087

Products guided by the article

Product name:3-Cyclohexene-1-carboxaldehyde, 1-(2-propenyl)-

Cas No:10420-49-2

R&D Labs maybe for 10420-49-2

Chengdu King-tiger Pharm-chem. Tech. Co., Ltd

Contact:028-85317716

Address:Tianfu Life Science Park, No. 88 South Keyuan Road, Gaoxin District, Chengdu City, Sichuan Province, PRC.
SunaTech Inc.

Contact:+86 512 6287 2180

Address:398 Ruoshui Road, Suzhou Industrial Park, Suzhou, Jiangsu, P. R. China
Zhengzhou Yuanli Biological Technology Co., Ltd.

Contact:+86-371-67897870/67897895

Address:No. 38, Qingyang Street, Zhengzhou, Henan, China
Suzhou Sinosun Imp.&Exp. Corporation

website:http://www.szsinosun.com

Contact:+86-512-63488895,63488616

Address:No.758 East Jiangling Road Wujiang Economic & Technological Developmenty Zone Jiangsu China
SICHUAN TONGSHENG AMINOACID CO.LTD

website:http://www.aminoacid.cc

Contact:86-838-2274206/2850606

Address:Room 1-11-1,No.19 of North TianShan Road,Deyang,Sichuan China

Relevant to this article

Synthesis of heterosteroids. First synthesis of oxa steroid from cholic acid

Doi:10.1016/j.tetlet.2009.10.141
(2010)
Facile photochemical synthesis of 1,1′-binaphthyls

Doi:10.1071/CH08141
(2008)
Bifunctional bisphosphonate derivatives and platinum complexes with high affinity for bone hydroxyapatite

Doi:10.1016/j.bmcl.2016.12.050
(2017)
Synthesis of complexes of Pb(II), Cd(II), Zn(II), Ni(II), La(III) and Cu(II) with a Schiff base macrocyclic ligand containing pyridine

Doi:10.3184/030823410X12744563061343
(2010)
Atrazine transformation using synthetic enzymes prepared by molecular imprinting.

Doi:10.1039/b407002j
(2004)
Construction of α,α-disubstituted α-Amino Acid Derivatives via aza-Morita-Baylis-Hillman Reactions of 2-Aminoacrylates with Activated Olefins

Doi:10.1002/cctc.201901987
(2020)

Article Doi