AN IMPROVED PROCEDURE FOR EFFICIENT GENERATION OF METHYL(OR p-TOLYL)THIOMETHYL GRIGNARD REAGENT AND ITS USE IN ORGANIC SYNTHESES

DOI: 10.1246/cl.1982.1697

Source and publish data:

Chemistry Letters p. 1697 - 1698 (1982)

Update date:2022-08-29

Topics:

Authors:

Ogura, Katsuyuki

Fujita, Makoto

Takahashi, Kazumasa

Iida, Hirotada

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1982.1697

The optimal condition for transformation of a chloromethyl sulfide into the corresponding Grignard reagent (2) in a high yield are established and 2 is shown to react with various functional groups such as an alkyl halide, an aldehyde, and a sulfinic este

Full text of DOI:10.1246/cl.1982.1697

Products guided by the article

Product name:trimethyl[(methylsulfanyl)methyl]silane

Cas No:10428-57-6

R&D Labs maybe for 10428-57-6

Shanghai Demand Chemical Co., ltd，China

Contact:86-021-55237578/55239122

Address:Room 3H, No.578, Yingkou Road, Yangpu District, Shanghai, China
Yingkou Sanzheng Organic Chemical Co. Ltd.

Contact:+86-417-3638818

Address:25 Gengxinli Village, Daqing Road, Yingkou, Liaoning, China
Shanggao Ruiya Fine Chemicals Co., Ltd

Contact:+86-795-2592103

Address:Xingguang Nanlu,Shanggao County Industry Park
TIANJIN FESTO CHEMICAL CO.,LTD(expird)

Contact:86-22-25814570

Address:No.12th,5th Ave.,TEDA,Tianjin,China
Beijing Mesochem Technology Co.,LTD

website:http://www.mesochem.com

Contact:0086-10-57862036

Address:2301, Floor 23, Building 9 Lippo Plaza, Yard 8 Ronghua Middle Road, ETDZ, Beijing, China

Relevant to this article

The OBrO C(²A₂)←X(²B₁) absorption spectrum

Doi:10.1063/1.474606
(1997)
Tuning the catalytic performance for the semi-hydrogenation of alkynols by selectively poisoning the active sites of Pd catalysts

Doi:10.1039/c9gc01356c
(2019)
Efficient conversion of fructose to 5-hydroxymethylfurfural by functionalized γ-Al₂O₃ beads

Doi:10.1002/aoc.4821
(2019)
Electrochemically driven stereoselective approach tosyn-1,2-diol derivatives from vinylarenes and DMF

Doi:10.1039/d1sc00760b
(2021)
Porous chitosan microspheres supported-palladium catalyst for the C-N cross-coupling of aryl halides with secondary amines

Doi:10.3184/174751913X13571448166475
(2013)
The unique crystallographic signature of a β-turn mimic nucleated by N-methylated phenylalanine and Aib as corner residue: Conformational and self-assembly studies

Doi:10.1039/c3ce41448e
(2013)

Article Doi