Tetrahedron p. 1627 - 1634 (1997)
Update date:2022-08-11
Topics:
Kobayashi, Yuichi
Takahisa, Eisuke
Nakano, Miwa
Watatani, Kengo
Reduction of aldehydes and ketones with PMHS [Me3SiO-(SiMe(H)O)(n)-SiMe3] proceeded smoothly in the presence of Bu4NF at -70°C or 0°C within 60 min in THF. High stereo- and chemoselectivities as well as functional group tolerance of this system are also presented.
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Doi:10.1021/ja01236a002
(1944)Doi:10.14233/ajchem.2020.22735
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