Zr-CATALYZED OXIDATION OF ALCOHOLS TO ALDEHYDES IN THE PRESENCE OF t-BuOOH. HIGH REACTIVITY FOR PRIMARY AND ALLYLIC HYDROXYL FUNCTIONS

DOI: 10.1246/cl.1984.1481

Source and publish data:

Chemistry Letters p. 1481 - 1482 (1984)

Update date:2022-08-22

Topics:

Authors:

Kaneda, Kiyotomi

Kawanishi, Yasuyuki

Teranishi, Shiichiro

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Article abstract of DOI:10.1246/cl.1984.1481

ZrO(OAc)2 catalyzes selective oxidation of primary alcohols to aldehydes without formation of carboxylic acids and also chemoselective oxidation of allylic alcohols to α,β-unsaturated aldehydes in the presence of t-BuOOH.

Full text of DOI:10.1246/cl.1984.1481

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