On the Active Species of Aluminium(III) Bromide-Copper(II) Bromide Mixtures as Catalysts for the Isomerization of Pentane

DOI: 10.1039/P29800001201

Source and publish data:

Journal of the Chemical Society. Perkin transactions II p. 1201 - 1205 (1980)

Update date:2022-08-11

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Authors:

Kitajima, Nobumasa

Sakuma, Shigeharu

Ono, Yoshio

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Article abstract of DOI:10.1039/P29800001201

Mixtures of AlBr3 and CuSO4 have high catalytic activity and selectivity for the isomerization of pentane at room temperature.The isomerization obeys the first-order kinetics with respect to pentane and proceeds both in the liquid phase and on the surface of copper(II) sulphate.The complex formed from the two substances seems responsible for the catalytic activity.

Full text of DOI:10.1039/P29800001201

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