Chiral Organometallic NADH Mimics: Stereoselective Reduction of Ethyl Benzoylformate Utilising the Homochiral Auxiliary 5-C5H5)Fe(CO)(PPh3)> at C-3 and a Chiral β-Hydroxy-carboxamide Derived from Valinol at C-5

DOI: 10.1039/c39900001759

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1759 - 1762 (1990)

Update date:2022-08-17

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Authors:

Burgess, Vicky A.

Davies, Stephen G.

Skerlj, Renato T.

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Article abstract of DOI:10.1039/c39900001759

Homochiral complexes incorporating the chiral auxiliary <(η⁵-C5H5)Fe(CO)(PPh3)> at C-3 and a chiral β-hydroxy-carboxamide, derived from valinol, at C-5 reduce ethyl benzoylformate to ethyl mandelate in greater than 97percent enantiomeric excess.

Full text of DOI:10.1039/c39900001759

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