SYNTHESIS OF 2-DEOXYXYLOLACTONE FROM GLYCEROL DERIVATIVES VIA HIGHLY ENANTIOSELECTIVE CARBON-HYDROGEN INSERTION REACTIONS

DOI: 10.1016/S0040-4039(00)76684-6

Source and publish data:

Tetrahedron Letters p. 3853 - 3856 (1994)

Update date:2022-08-25

Topics:

Authors:

Doyle, Michael P.

Dyatkin, Alexey B.

Tedrow, Jason S.

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Article abstract of DOI:10.1016/S0040-4039(00)76684-6

diazodecomposition of 1,3-dialkoxy-2-propyl diazoacetates catalyzed by chiral dirhodium(II) carboxamides results in highly enantioselective and diastereoseelctive carbon-hydrogen insertion which forms 3,5-dialkyl 2-deoxyxylolactones in up to 98percent enantiomeric excess.

Full text of DOI:10.1016/S0040-4039(00)76684-6

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