SYNTHESIS OF 2-DEOXYXYLOLACTONE FROM GLYCEROL DERIVATIVES VIA HIGHLY ENANTIOSELECTIVE CARBON-HYDROGEN INSERTION REACTIONS

DOI: 10.1016/S0040-4039(00)76684-6

Source and publish data:

Tetrahedron Letters p. 3853 - 3856 (1994)

Update date:2022-08-25

Topics:

Authors:

Doyle, Michael P.

Dyatkin, Alexey B.

Tedrow, Jason S.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)76684-6

diazodecomposition of 1,3-dialkoxy-2-propyl diazoacetates catalyzed by chiral dirhodium(II) carboxamides results in highly enantioselective and diastereoseelctive carbon-hydrogen insertion which forms 3,5-dialkyl 2-deoxyxylolactones in up to 98percent enantiomeric excess.

Full text of DOI:10.1016/S0040-4039(00)76684-6

Products guided by the article

Product name:3,4-trans(erythro)-3,5-dihydroxy-4-pentanolide

Cas No:106357-04-4

R&D Labs maybe for 106357-04-4

XinChem Corporation

Contact:+86 21 34123252

Address:14, 4580 Dushi, Shanghai, China
guide(suzhou) fine materials co. ltd

Contact:0512-80972173

Address:21st Building, No.369 Lushan Rd, New District Suzhou China 215129
Huangshi Meifeng Chemical Co.,ltd.

Contact:+86-714-6516706

Address:1941-4-3#,Hubin Avenue,Huangshi,Hubei,China
ZiBO KuoDing Trade company Ltd

website:http://www.sdzbkd.com

Contact:86-13361591822

Address:GongQingTuan road
New Forms

Contact:+31-24-3886056

Address:Binderskampweg 29 Unit 36

Relevant to this article

Hydroboration of Terpenes. 9. A Simple Improved Procedure for Upgrading the Optical Purity of Commercially Available α- and β-Pinenes. Conversion of (+)-α-Pinene to (+)-β-Pinene via Hydroboration-Isomerisation.

Doi:10.1021/jo00252a032
(1988)
Phosphoramidite building blocks with protected nitroxides for the synthesis of spin-labeled DNA and RNA

Doi:10.3762/bjoc.14.133
(2018)
Doi:10.1021/bi00625a005
(1977)
Nucleophilic Aromatic Substitution by Paired Electrosynthesis: Reactions of Methoxy Arenes with 1H-Tetrazoles

Doi:10.1016/0040-4039(95)01455-Q
(1995)
Poly[[μ₂-1,3-bis-(pyridin-4-yl)-propane](μ₃-1, 4-phenyl-ene-diacetato)-cadmium]

Doi:10.1107/S0108270111055454
(2012)
Doi:10.1080/00304940209355785
(1950)

Article Doi