Stereochemical Rigidity of the Square-pyramidal W(CO)5 Moiety during 1,2- and 1,3-Metallotropic Shifts in Sulphur Ligand Complexes

DOI: 10.1039/DT9880001489

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1489 - 1492 (1988)

Update date:2022-08-16

Topics:

Authors:

Abel, Edward W.

Moss, Ian

Orrell Keith G.

Qureshi, Khurshid B.

Sik, Vladimir

Stephenson, David

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Article abstract of DOI:10.1039/DT9880001489

N.m.r. studies of tungsten pentacarbonyl complexes of type where L refers to openchain ligands (PhCH2SSCH2Ph or MeSCH2SMe) and cyclic ligands <β-cyclo(CHMeSCHMeSC)HMe, or cyclo(SCMe2SCH2C)H2> have revealed no evidence of carbonyl scrambling acco

Full text of DOI:10.1039/DT9880001489

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