A new and facile synthetic route to 1-alkyl-2-oxopropylphosphonates: 1 alkylation with subsequent ozonolysis of 2-methyl allylic phosphonates

Article abstract of DOI:10.1080/00397919808004906

Alkylation of the 2-methyl allylic phosphonates is performed by treatment with n-BuLi, followed by addition of alkyl halides. The 1-alkyl-2- oxopropylphosphonates are obtained by the ozonolysis of the corresponding allylic phosphonates.

Full text of DOI:10.1080/00397919808004906

Synthetic Communications
ISSN: 0039-7911 (Print) 1532-2432 (Online) Journal homepage: http://www.tandfonline.com/loi/lsyc20
A New and Facile Synthetic Route to 1-Alkyl-2-
Oxopropylphosphonates : 1-Alkylation with
Subsequent Ozonolysis of 2-Methyl Allylic
Phosphonates
Jun MoGil , Kwang YoungPark , Jung HwanHah & Dong YoungOh
To cite this article: Jun MoGil , Kwang YoungPark , Jung HwanHah & Dong YoungOh (1998)
A New and Facile Synthetic Route to 1-Alkyl-2-Oxopropylphosphonates : 1-Alkylation with
Subsequent Ozonolysis of 2-Methyl Allylic Phosphonates, Synthetic Communications, 28:19,
3601-3607, DOI: 10.1080/00397919808004906
To link to this article: http://dx.doi.org/10.1080/00397919808004906
Published online: 22 Aug 2006.
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Date: 08 February 2016, At: 23:53