Journal of Organic Chemistry p. 307 - 313 (2019)
Update date:2022-08-11
Topics:
Zhang, Tao
Chen, Fan
Zhang, Xiao-Hong
Qian, Peng-Cheng
Zhang, Xing-Guo
A palladium-catalyzed tandem cyclization and cross-coupling reaction of o-(2-chlorovinyl)alkynylbenzenes with indoles/pyrroles is developed. The process proceeds via intramolecular carbocyclization and subsequent hetroarylation to afford previously unknown trifluoromethyl-containing indenylmethyleneindoles, which are potentially useful in drug design.
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