Managense(III)-catalysed oxidation of sulphides with sodium chlorite in an aprotic solvent in the presence of alumina

Article abstract of DOI:10.1080/00397919608003540

A wide variety of sulphides can be readily converted to the corresponding sulphoxides in good to excellent yields by treatment with a combination of sodium chlorite, (salen)manganese(III) complex, and chromatographic alumina in dichloromethane under mild and neutral conditions.

Full text of DOI:10.1080/00397919608003540

This article was downloaded by: [University of Chicago Library]
On: 25 December 2014, At: 23:01
Publisher: Taylor & Francis
Informa Ltd Registered in England and Wales Registered Number: 1072954
Registered office: Mortimer House, 37-41 Mortimer Street, London W1T 3JH,
UK
Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
Publication details, including instructions for
authors and subscription information:
http://www.tandfonline.com/loi/lsyc20
Manganese(III)-Catalysed
Oxidation of Sulphides with
Sodium Chlorite in an Aprotic
Solvent in the Presence of
Alumina
a
a
Masao Hirano , Shigetaka Yakabe , James H. Clark
b
a
a
,
Hiroyuki Kudo & Takashi Morimoto
a
Department of Applied Chemistry, Faculty of
Technology , Tokyo University of Agriculture and
Technology , Koganei, Tokyo, 184, Japan
b
Department of Chemistry , University of York ,
Heslington, York, UK , YO1 5DD
Published online: 21 Aug 2006.
To cite this article: Masao Hirano , Shigetaka Yakabe , James H. Clark , Hiroyuki
Kudo & Takashi Morimoto (1996) Manganese(III)-Catalysed Oxidation of Sulphides
with Sodium Chlorite in an Aprotic Solvent in the Presence of Alumina, Synthetic
Communications: An International Journal for Rapid Communication of Synthetic
Organic Chemistry, 26:10, 1875-1886, DOI: 10.1080/00397919608003540
To link to this article: http://dx.doi.org/10.1080/00397919608003540
PLEASE SCROLL DOWN FOR ARTICLE
Taylor & Francis makes every effort to ensure the accuracy of all the
information (the “Content”) contained in the publications on our platform.

However, Taylor & Francis, our agents, and our licensors make no
representations or warranties whatsoever as to the accuracy, completeness,
or suitability for any purpose of the Content. Any opinions and views
expressed in this publication are the opinions and views of the authors, and
are not the views of or endorsed by Taylor & Francis. The accuracy of the
Content should not be relied upon and should be independently verified with
primary sources of information. Taylor and Francis shall not be liable for any
losses, actions, claims, proceedings, demands, costs, expenses, damages,
and other liabilities whatsoever or howsoever caused arising directly or
indirectly in connection with, in relation to or arising out of the use of the
Content.
This article may be used for research, teaching, and private study purposes.
Any substantial or systematic reproduction, redistribution, reselling, loan,
sub-licensing, systematic supply, or distribution in any form to anyone is
expressly forbidden. Terms & Conditions of access and use can be found at
http://www.tandfonline.com/page/terms-and-conditions