Journal of the American Chemical Society
Page 12 of 14
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1 5) R oer in g , A . J. ; H a le, L . V . A .; Squ ie r, P. A .; R in g gol d, M . A . ;
W ie der sp an , E. R .; Cl a rk , T. B . t. 2 0 1 2 , 4, 3558 -3 561 .
1 6) K u n i n ob u , Y .; I d a , H .; N is h i , M .; K a n a i, M . A m et a -s e le ct iv e C -H
b ory l at io n d ir ec ted b y a sec on da ry in t era c t io n b e tw een l ig an d an d
su b st ra t e. . 2 0 1 5 , 7, 71 2 -7 1 7.
1 7) L u , X. ; Y osh ig o e, Y .; Id a , H .; N is h i , M .; K a n a i, M .; K u n in ob u , Y.
(3 3) R e n , H .; Z h ou , Y . -P .; B a i, Y .; C u i, C .; D r ie ss, M . C ob al t ‐C atal yze d
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R e g io se le ct iv e B or yl at io n of A r en e s: N ‐H ete r ocy cl ic S il yl en e as an
E le ct ron D on or in th e M e tal‐M e d ia te d A c t iv a t io n of C − H Bo n ds.
C h e m . E u r . J . 2 0 1 7 , 23 , 5663 -5 667.
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(3 4) Ob l ig a c io n , J . V .; S em pr on i, S . P .; P ap pas, I . ; C h ir ik , P . J . C ob al t-
C at aly z e d C (sp 2) -H B or yl at io n : M e ch an is t ic In s ig h ts I n sp ir e C ata-
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H yd rogen B on d -A c c elera t ed m et a -S elec t iv e C -H B ory la t io n of A r -
om a t ic Co m p ou n ds a n d E xp ress io n of F u n c t io n a l G r ou p an d S u b -
st ra t e Sp ec if ic it ie s . A CS Ca t a l. 2 0 1 9 , 9, 1 70 5 -1 70 9.
ly st D e s ig n .
3 5) Ob l ig a c io n , J . V .; C h ir ik , P . J . M e c h an is t ic S tu d ie s o f C ob al t-
C at aly z e d C (sp 2) – H B or yl at io n of F iv e -M e m b e re d H e t e r oar en e s
w it h P in ac olb oran e . . 2 0 1 7 , 7, 4366 – 4371 .
3 6) L i, H .; Ob l ig a c io n , J . V .; C h ir ik , P . J . ; H all , M . B . C ob al t P in ce r
C om pl exe s in C atal y t ic C – H B or yl at io n : T h e P in c e r L ig an d Fl ip s
R at h er T h a n D e ar om at iz es. . 2 0 1 8 , 8, 1 0 60 6 – 1 0 61 8.
3 7) B u r és, J . V ar ia b l e T im e N orm al iz at io n A n aly s is : G en e ra l G r aph ic al
E lu c id at io n of R e act i o n Or de rs f rom C on c en tr at io n P r of il e s.
. 2 0 1 6 , 5 , 1 60 84 -1 60 87 .
3 8) T h e f ray in g of th e V TN A ov er lay pl ot f or 2a at h ig h co n v e rs i o n i n -
J . A m . C h e m . Soc . 2 0 1 6 , 1 38 , 1 0 645 -1 0 653.
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( 1 8) D a v is , H . J. ; G en ov , G . R .; Ph ip p s, R . J . m et a -S elec t iv e C − H B or yl a-
t io n of B en zyl a m in e -, Ph en et h y l am in e -, a n d Ph en y l pr opy la m in e -
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D e r iv ed A m id es E n a b l ed b y a S in g le A n io n ic L ig an d .
d. 2 0 1 7 , 6 , 1 3351 -1 3355.
1 9) D a v is , H . J. ; M ih a i, M . T. ; Ph ip p s, R . J . Io n Pa ir -D ir ec t ed R e g io con -
t rol in T ra n s it io n -M et a l Ca t a ly s is : A M et a -S elec t iv e C – H B ory la -
t io n of A rom at ic Q u at ern a ry A m m on iu m Sa lt s .
0 1 6 , 8 , 1 2759 -1 2762.
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( 20 ) M ih a i, M . T .; D a v is , H . J . ; G en ov , G . R .; Ph ip p s, R . J . I o n P a ir -
D i r ec t ed C – H A c t iv at io n on F l ex ib l e A m m on iu m Sa lts : m e ta -
Se lec t iv e B ory l at io n of Q u a t ern iz ed Ph en et h yl a m in e s an d P h e -
d ic at es sat u r a t io n b e h av io r ; a d is cu ss io n of th is b e h av io r can b e
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3 9) N ee ly , J . M .; B ez de k , M . J . ; C h ir ik , P . J. I n s ig h t in t o T r an sm e t ala t i o n
E n ab l es C ob al t -C atal y ze d S u zu k i– M iy au ra C ross C ou p l i n g.
. 2 0 1 6 , 2, 935 -9 42.
4 0 ) T h e pr es en c e of a d eu t er iu m at om
n y l pr opyl a m in e s.
21 ) H oqu e, M . E. ; B is h t , R .; H a lda r , C. ; C h a t t opa dh ya y , B . N on c o v a le n t
I n t er ac t io n s in Ir -C a t a l yz ed C– H A c t iv a t io n : L -S h a ped L ig an d f or
Pa r a -S e lec t iv e B ory l at i o n of A rom a t ic E st er s. c.
0 1 7 , 9 , 7745 -7 748.
22) Ch a t to pa d h ya y , B .; D a n n a t t , J . E .; A n du j a r -D e Sa n c t is , I . L .; G ore ,
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pe rm it s f ac il e qu a n t i f ic at io n of d eu ter iu m in c or porat i o n i n t h e e x-
pe r im en ts d escr ib e d .
K . A .; M a l ec z k a , R . E .; S in g let on , D . A .; Sm it h , M . R . I r -C at aly z e d
ort h o -B ory l at io n of Ph en ol s D ir ec t ed b y Su b s t ra t e– L ig an d E le ct ro-
st a t ic I n t era c t io n s : A Com b in e d E xp er im en t a l / in S il ic o S tr at egy f or
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864 − 7871 .
2 3) Sm it h , M . R .; B i s h t , R .; H a lda r, C .; Pa n de y, G .; D a n n a t t , J . E .; G h af-
J . A m . Ch em . Soc . 2 0 1 7 , 1 39 ,
s it io n M e tal S pec ie s f rom a C om pu t at io n a l P er spect iv e .
0 1 0 , 0 , 749 -8 23.
4 2) C lot , E .; E is e n st e in , O.; J a s im , N .; M a c G re gor , S . A . ; M cG r ady , J . E. ;
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f a r i, B .; M a l ec z k a , R . E .; Ch a t t opa dh y a y , B . N on c ov a l en t In te r ac-
t io n s in I r -C a t al y ze d C – H A c t iv at io n : L -S h a ped L ig an d f or P ar a -
P er u t z, R . N . C − F an d C − H B on d A c t i v at io n of F lu o ro b en z e n es
an d F lu or opy r id in e s at T ran s it io n M e ta l C en te r s: H ow Fl u or in e
Se lec t iv e B ory l at io n of A rom a t ic E st er s.
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2 4) R oosen , P. C. ; K al lepa l l i, V . A .; Ch a t t opa dh yay , B .; S in g le ton , D . A . ;
M a l ec z k a, R . E. ; Sm it h , M . R . Ou t er -S ph ere D ir ec t io n in I r id iu m C –
H B ory l at io n . c. 2 0 1 2 , 4 , 1 1 350 -1 1 353.
25) B is h t , R .; Ch a t top ad h y ay , B . F orm a l Ir -C a t a l y zed L ig an d -E n ab le d
Ort h o a n d M et a B ory l a t io n of A rom a t ic A l deh y des v i a in S it u -
G en er at ed I m in e s. . 2 0 1 6 , 8 , 84 -8 7.
26) W a n g , J. ; Sá n c h ez -R osel ló, M .; A c eñ a , J . L .; de l Poz o, C .; S o-
t i v it y in th e ac t iv at io n of f lu or in at e d ar om at ic h y dr oc arb on s b y r h o -
d iu m co m ple xe s [ (C 5H 5) R h (PM e 3) ] an d [ (C 5M e 5) R h ( PM e 3) ] .
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4 4) C lot , E .; B es ora , M .; M a se ra s, F .; M é gr et , C .; E i s e n st e in , O .;
Oe lc k e rs, B .; P er u t z, R . N . n . 2 0 0 3 , 490 -4 91 .
4 5) C lot , E .; Oe lc k e rs, B .; K lah n , A . H .; E is e n st e in , O.; P e ru t z, R . N .
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m e n ta l ap proac h to th e se n s it iv it y of M – C b on d str e n gt h t o su b st it -
u e n t s. D alto n T r an s. 2 0 0 3 , 40 65 -4 0 74.
roc h in sk y , A . E. ; F u st ero , S.; Solosh o n ok , V . A .; L iu , H . F lu or in e in
Ph a rm a c eu t i c a l In du st ry : F l u or in e -C on t a in in g D ru gs In t rod u c ed to
t h e M a rk e t in t h e L a st D ec a de (20 0 1 – 20 1 1 ) .
4 , 2432 -2 50 6.
27) E i s en st e in , O.; M il an i, J . ; Per u t z, R . N . Selec t iv it y of C – H A c t i v at i o n
a n d Co m p et it io n b e tw een C – H a n d C – F B on d A c t iv at io n at F lu o-
roc a r b on s. v . 2 0 1 7 , 7 , 871 0 -8 753
28) K a l län e , S. I . ; Tel t ew sk i, M .; B ra u n , T. ; B ra u n , B . C – H an d C– F
B on d A c t iv a t io n s a t a R h od iu m ( I) Bory l Com pl ex: R eac t io n S te ps
f or t h e Ca t a l yt ic B ory l a t io n of F l u or in a t ed A rom a t ic s.
s 2 0 1 5 , 4 , 1 1 56 -1 1 69.
29) Ob l ig ac io n , J. V .; B ezdek , M . J . ; Ch ir ik , P. J . C( s p2) – H Bor yl at io n
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(4 6) C lot , E .; M é gr et , C .; E is e n st e in , O.; P er u t z, R . N . V al i d at io n o f t h e
M − C/ H − C B on d En th al py R e lat io n sh ip th r ou g h A pp l i c at io n of
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D e n s it y F u n c t i o n al T h e ory .
357.
4 7) C lot , E .; M é gr et , C .; E is e n st e in , O.; P er u t z, R . N . E x ce pt i o n al S e n s i-
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I n f lu e n ce of th e M e ta l, th e C oord in a t io n S ph e re , an d t h e S pe ct at or
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(4 8) E v a n s, M . E .; B u r k e , C . L .; Ya ib u at h es, S .; C lot , E .; E is en ste i n , O .;
J o n e s, W . D . E n e rg et ic s of C − H B on d A c t i v at io n of F lu or in at e d A r-
of F l u or in a t ed A ren e s U s in g a n A ir -S t a b l e Cob a lt Pre ca tal y st: E le c-
t ron i c all y En h an c ed S it e Selec t iv it y E n ab l es Sy n t h et ic Oppor tu n i-
om at ic H y dr oc arb on s U s in g a [ Tp ’R h (C N n eopen ty l) ] C om p le x.
c. 2 0 0 9 , 1 , 1 3464 -1 3473.
4 9) C h a i, J . -D .; H ea d -G ordon , M . L on g -r an ge co rre ct ed h yb r id de n s it y
f u n c t io n als w it h d a m pe d at om – at om d is pe rs io n co rre ct i o n s.
. 2 0 0 8 , 0 , 661 5 -6 620 .
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30 ) F u r u k a w a , T .; Tob is u , M .; Ch a t a n i, N . C – H F u n c t io n al iz at io n at
St e r ic a lly Co n ge st ed Pos it io n s b y t h e Pl a t in u m -C a ta l y ze d B or yl a-
t io n of A ren es. c. 2 0 1 5 , 7 , 1 221 1 -1 221 4.
J. A m . Ch em . Soc . 2 0 1 7 , 1 39 , 2825 -2 832.
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( 31 ) T ak aya , J. ; I t o, S.; N om ot o, H .; Sa it o, N .; K ir a i, N .; I w a saw a, N .
F l u or in e -c on t r oll ed C – H b or yl a t io n of a ren es c a ta l yzed b y a P S iN -
p in cer p la t in u m c om p lex .
32) Ob l ig ac io n , J. V .; Sem pro n i, S. P. ; Ch i r ik , P. J . Cob a lt -C at aly z e d C–
H B ory l at io n . . 2 0 1 4 , 6 , 41 33 -4 1 36.
Ch em . Com m u n . 2 0 1 5 , 51 , 1 7662 -1 7665.
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