Oxovanadium-induced oxidative desilylation of allylic and benzylic silanes

DOI: 10.1016/S0040-4039(00)73892-5

Source and publish data:

Tetrahedron Letters p. 5601 - 5604 (1993)

Update date:2022-08-16

Topics:

Authors:

Fujii, Takashi

Hirao, Toshikazu

Ohshiro, Yoshiki

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Article abstract of DOI:10.1016/S0040-4039(00)73892-5

Cinnamyltrimethylsilane underwent desilylation via one-electron oxidation with VO(OEt)Cl₂, which was applied to the cross-coupling with the less oxidizable allylic silanes to give the corresponding 1,5-hexadienes. Chlorination or aromatization

Full text of DOI:10.1016/S0040-4039(00)73892-5

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