A NEW EFFICIENT SYNTHESIS AND REARRANGEMENTS OF PARACYCLOPHANE

DOI: 10.1246/cl.1983.1645

Source and publish data:

Chemistry Letters p. 1645 - 1646 (1983)

Update date:2022-08-11

Topics:

Authors:

Tobe, Yoshito

Ueda, Ken-ichi

Kakiuchi, Kiyomi

Odaira, Yoshinobu

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1983.1645

<6>paracyclophane (1) has been synthesized by oxidative decarboxylation of <6.2.2>propellenecarboxylic acid with lead tetraacetate.Vapor phase thermolysis of 1, affords 3-methylenespiro<5.5>undeca-1,4-diene predominantly, while acid-catalyzed rearrangement of 1 gives the meta and ortho isomers in ratio of 1:3.

Full text of DOI:10.1246/cl.1983.1645

Products guided by the article

Product name:bicyclo[6.4.0]dodeca-8,10,12-triene

Cas No:1076-69-3

R&D Labs maybe for 1076-69-3

SHANGHAI BIOSUNDRUG CO.,LTD.

Contact:86-21-34622192，13917187091，21-34622765

Address:No. 500 Caobao Road Shanghai P.R China
MS( MAOSHENG )Chemical CO.,LTD

Contact:+86-519-82726678.82726378

Address:TAOXI INDUSTRY ZONE JINTAN
Kaiping Genuine Biochemical Pharmaceutical Co.,Ltd.

Contact:+86-750-2881198

Address:No.1, Xinke Road, Shatang Town, Kaiping, Guangdong Province, P.R.China
Valiant Fine Chemicals Co., Ltd.

Contact:+86 535 6101878/6374484

Address:11 Wuzhishan Rd.,YTETDZ,Yantai,264006,Shandong,China
Anhui Sunsing Chemicals Co.,Ltd

website:http://www.sunsingchem.com

Contact:0086-566-2023179

Address:Jin An industry park, Chizhou economic technical development zone, Anhui

Relevant to this article

Metabolism, excretion, and pharmacokinetics of (3,3-difluoropyrrolidin-1- yl)((2s,4s)-4-(4-(pyrimidin-2-yl)piperazin-1-yl)pyrrolidin-2-yl)methanone, a dipeptidyl peptidase inhibitor, in rat, dog and human

Doi:10.1124/dmd.112.047316
(2012)
Heterometallic Cu^IIFe^III and Cu^IIMn^III alkoxo-bridged complexes revealing a rare hexanuclear M₆(μ-X)₇(μ₃-X)₂ molecular core

Doi:10.1039/c8dt02290a
(2018)
Doi:10.1139/v57-107
(1957)
Synthesis and characterization of Se-adenosyl-L-selenohomocysteine selenoxide

Doi:10.1080/17415993.2014.979173
(2015)
Synergy between the metal nanoparticles and the support for the hydrogenation of functionalized carboxylic acids to diols on Ru/TiO₂

Doi:10.1039/c0cc05206j
(2011)
Synthesis and photochemical studies of 2-nitrobenzyl-caged N-hydroxysulfonamides

Doi:10.1016/j.jphotochem.2019.112033
(2019)

Article Doi