Facile Conversion of Aldehydes into 1-Substituted 2-Chloro-3,3-difluoro-2-propen-1-ols with 1,1-Dibromo-1-chloro-2,2,2,-trifluoroethane/Magnesium Reagent

DOI: 10.1246/bcsj.61.3321

Source and publish data:

Bulletin of the Chemical Society of Japan p. 3321 - 3322 (1988)

Update date:2022-08-24

Topics:

Authors:

Fujita, Makoto

Hiyama, Tamejiro

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Article abstract of DOI:10.1246/bcsj.61.3321

Aldehydes RCHO are converted in excellent yields into chlorodifluoroallyl alcohols RCH(OH)CCl=CF2 upon treatment with CClBr2CF3 and magnesium in tetrahydrofuran at 0 deg C.

Full text of DOI:10.1246/bcsj.61.3321

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