Chemistry Letters p. 1361 - 1362 (1981)
Update date:2022-08-11
Topics:
Takahashi, Mitsuru
Ishii, Norio
Suzuki, Hiroharu
Moro-Oka, Yoshihiko
Ikawa, Tsuneo
Palladium(II) complexes, such as (CH3CN)2PdCl2 and (diene)PdCl2, catalyze 1,3-alkyl migration of 1-alkenyl ethyl acetals and subsequent elimination of ethanol to give α-alkylated (E)-α,β-unsaturated carbonyl compounds in excellent yields.
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