Chemical Communications p. 2745 - 2746 (1996)
Update date:2022-08-28
Topics:
Kashiwagi, Yoshitomo
Yanagisawa, Yoshinori
Kurashima, Futoshi
Anzai, Jun-Ichi
Osa, Tetsuo
Bobbitt, James M.
The S-isomers of four racemic sec-alcohols, which possess a chiral centre at the α-position to the hydroxy group, were oxidized to the corresponding ketones whereas the R-isomers remained unreacted on a TEMPO-modified graphite felt electrode in the presence of (-)-sparteine, where the enantiopurity of the remaining R-isomers was >99% and the current efficiency for the produced ketones was >90%.
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Doi:10.1016/j.bmc.2017.04.024
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