Journal of Organometallic Chemistry p. 73 - 77 (2018)
Update date:2022-08-25
Topics:
Khusainova, Liliya I.
Khafizova, Leila O.
Tyumkina, Tatyana V.
Ryazanov, Kirill S.
Popodko, Natalya R.
Dzhemilev, Usein M.
The one-pot cycloboration of α-olefins (oct-1-ene, dec-1-ene) for a facile access to substituted boriranes has been carried out with the use of alkyl, arylalkyl, and cycloalkyl boron dichlorides (EtBCl2, n-PentBCl2, n-HexBCl2, Ph(CH2)2BCl2, cyclo-OctBCl2, 2-norbornylBCl2) under Cp2TiCl2 catalysis.
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