Journal of the Chemical Society. Chemical communications p. 1250 - 1252 (1986)
Update date:2022-08-16
Topics:
Sasson, Y.
Weiss, M.
Loupy, A.
Bram, G.
Pardo, C.
The equilibrium position of the phase transfer catalysed exchange reaction RCl + MBr -->/<-- RBr + MCl where R = primary alkyl group and M = Li, Na, K, Ca is strongly dependent on the nature of the metal cation M and the amount of water present in the reaction mixture; this has been applied in the synthetic use of the reaction in both directions.
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