Organometallics p. 204 - 206 (1987)
Update date:2022-08-17
Topics:
Van Voorhees, Seth L.
Wayland, Bradford B.
The dimeric complex (RhII(TMTAA))2 (1) (TMTAA = dibenzotetramethylaza[14]annulene dianion) reacts with mixtures of hydrogen and carbon monoxide gases to produce a metallo hydride, RhIII(TMTAA)(H) (2), and an η1-metallo formyl complex, RhIII(TMTAA)(CHO). Compounds 1 and 2 react with ethene to produce bridging and terminal alkyl complexes, respectively.
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