Tetrahedron p. 1833 - 1838 (1989)
Update date:2022-08-16
Topics:
Batllori, Rosa
Font, Josep
Monsalvatje, Montserrat
Ortuno, Rosa M.
Sanchez-Ferrando, Francisco
Chiral butenolides are revealed to be good dienophiles in Diels-Alder reactions with cyclopentadiene, affording endo and exo adducts, whose fully characterization is provided.Selectivity of these cycloaddition reactions has been shown to be temperature dependent not as a result of a thermodynamic equilibrium between the isomers, but due to a kinetically controlled process.
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