RADIATION-INDUCED HYDROXYLATION OF THYMINE SENSITIZED BY NITRO COMPOUNDS IN N2O-SATURATED AQUEOUS SOLUTION

DOI: 10.1246/cl.1982.1041

Source and publish data:

Chemistry Letters p. 1041 - 1044 (1982)

Update date:2022-08-11

Topics:

Authors:

Wada, Takeshi

Ide, Hiroshi

Nishimoto, Sei-ichi

Kagiya, Tsutomu

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Article abstract of DOI:10.1246/cl.1982.1041

Hydroxylation of thymine (1) to give thymine glycol (3) is remarkably promoted by the addition of nitro compounds (2a-f) in the γ-radiolysis of the N2O-saturated aqueous solution, although overall decomposition of 1 is depressed to some extent.The G-value of 3 increases linearly with increasing the one-electron reduction potential of 2a-f.

Full text of DOI:10.1246/cl.1982.1041

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