Allylation of aldehydes and ketones with allyl bromide and tin promoted by Me3SiCl and alcohol

Article abstract of DOI:10.1080/00397919508011441

Allylation of aldehydes and ketones to give homoallylic alcohols can be carried out successfully with allyl bromide and metallic tin under anhydrous condition. The 64 ~ 89% yields of homoallyl alcohols are obtained by addition of chlorotrimethylsilane as a promoter in anhydrous methanol.

Full text of DOI:10.1080/00397919508011441

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Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
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Allylation of Aldehydes and
Ketones with Allyl Bromide and
Tin Promoted by Me SiCI and
3
Alcohol
a
a
a
Jing-Yao Zhou , Xu-Bo Yao , Zhao-Gen Chen
&
a
Shi-Hui Wu
a
Department of Chemistry , Fudan University ,
Shanghai, 200433, China
Published online: 16 Feb 2007.
To cite this article: Jing-Yao Zhou , Xu-Bo Yao , Zhao-Gen Chen & Shi-Hui Wu
(1995) Allylation of Aldehydes and Ketones with Allyl Bromide and Tin Promoted
by Me SiCI and Alcohol, Synthetic Communications: An International Journal for
3
Rapid Communication of Synthetic Organic Chemistry, 25:19, 3081-3087, DOI:
10.1080/00397919508011441
To link to this article: http://dx.doi.org/10.1080/00397919508011441
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