Synthesis of alkenyl- and aryldifluoroacetate using a copper complex from ethyl bromodifluoroacetate

DOI: 10.1248/cpb.47.1013

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1013 - 1016 (1999)

Update date:2022-08-28

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Authors:

Sato, Kazuyuki

Kawata, Ryuichi

Ama, Fumitaka

Omote, Masaaki

Ando, Akira

Kumadaki, Itsumaro

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Article abstract of DOI:10.1248/cpb.47.1013

Ethyl bromodifluoroacetate reacted with alkenyl or aryl iodides in the presence of copper powder in dimethyl sulfoxide (DMSO) to give the corresponding alkenyl- or aryldifluoroacetates in moderate to good yields.

Full text of DOI:10.1248/cpb.47.1013

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