Chemistry Letters p. 23 - 26 (1982)
Update date:2022-08-29
Topics:
Hirai, Kenji
Suzuki, Hiroharu
Kashiwagi, Hiroshi
Moro-Oka, Yoshihiko
Ikawa, Tsuneo
γ-Ketoesters are obtained in excellent yields by means of double bond migration of 2,5-dimethoxy-2,5-dihydrofurans mediated by a ruthenium hydride complex, HRuCl(PPh3)3(C6H5CH3) or HRuCl(CO)(PPh3)3, and subsequent hydrolysis in acidic media.
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