FURTHER STUDIES ON THE STEREOCHEMISTRY OF METAL ENOLATE-IMINE CONDENSATION REACTIONS

DOI: 10.1016/S0040-4039(00)95486-8

Source and publish data:

Tetrahedron Letters p. 3257 - 3260 (1987)

Update date:2022-08-15

Topics: applications Mechanistic Studies Asymmetric Induction Chirality transfer Substrate Scope Dynamic Kinetic Resolution Mechanistic Insights Computational Studies Synthetic Strategies Catalyst Development

Authors:

Iwasaki, Genji

Shibasaki, Masakatsu

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Article abstract of DOI:10.1016/S0040-4039(00)95486-8

Biscyclopentadienylchlorozirconium enolates derived from S-tert-butyl alkanethioates condensed with the imine 1 in a syn selective manner, while the diethylaluminum enolates derived from S-tert-butyl propanethioate and S-tert-butyl butanethioate reacted 1 in an anti selective manner.

Full text of DOI:10.1016/S0040-4039(00)95486-8

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Product name:(2S,3S)-2-Isopropyl-3-(4-methoxy-benzylamino)-5-trimethylsilanyl-pent-4-ynethioic acid S-tert-butyl ester

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