Tetrahedron Letters p. 3257 - 3260 (1987)
Update date:2022-08-15
Topics: applications Mechanistic Studies Asymmetric Induction Chirality transfer Substrate Scope Dynamic Kinetic Resolution Mechanistic Insights Computational Studies Synthetic Strategies Catalyst Development
Iwasaki, Genji
Shibasaki, Masakatsu
Biscyclopentadienylchlorozirconium enolates derived from S-tert-butyl alkanethioates condensed with the imine 1 in a syn selective manner, while the diethylaluminum enolates derived from S-tert-butyl propanethioate and S-tert-butyl butanethioate reacted 1 in an anti selective manner.
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