SYNERGISTIC EFFECT OF HOMOGENEOUS RUTHENIUM-RHODIUM CATALYSTS FOR METHANOL HOMOLOGATION

DOI: 10.1016/0022-328X(86)80365-5

Source and publish data:

Journal of Organometallic Chemistry p. 227 - 230 (1986)

Update date:2022-08-12

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Authors:

Pursiainen, Jouni

Karjalainen, Kauko

Pakkanen, Tapani A.

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Article abstract of DOI:10.1016/0022-328X(86)80365-5

Homogeneous solutions containing both ruthenium and rhodium complexes and methyl iodine are shown to exhibit a synergistic effect for the homologation of methanol to ethanol.Reactions were studied at pressures from 100 to 175 atm and at temperatures from 160 to 240 deg C.The highest selectivities were obtained with excess of ruthenium complexes present.Under these reaction conditions no evidence for cluster catalysis was found.

Full text of DOI:10.1016/0022-328X(86)80365-5

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