Kinetics of Gas Phase Addition Reactions of Trichlorosilyl Radicals. IV. Relative Rates of Additions to 1-Alkenes

Article abstract of DOI:10.1246/bcsj.55.323

Trichlorosilyl radical additions to a mixture of ethene, propene, 1-butene, and 1-pentene and to a mixture of propene and 2-methylpropene have been investigated.The rate of adduct formation from each olefin was obtained relative to that from propene between 403 K and 548 K.These relative rates are in good agreement with those calculated from the rate parameters obtained previously in this laboratory.