Chemistry Letters p. 2299 - 2300 (1987)
Update date:2022-08-29
Topics:
Saheki, Yukitami
Sasada, Katsuhiko
Satoh, Nobumasa
Kawaichi, Noriyuki
Negoro, Kenji
Dimethyl ether of acyclic polyethers, Me(OCH2CH2)nOMe, preodominantly coordinated to MgX2 in an ether solution of Grignard reagent and the MgX2 adduct was removed as a precipitate.Consequently, an ethereal solution of pure R2Mg was obtained in reasonable yield.This method is more convenient than those known general.
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