Journal of the Chemical Society. Chemical communications p. 484 - 485 (1980)
Update date:2022-08-10
Topics:
Beckwith, Athelstan L. J.
Lawrence, Tony
Serelis, Algirdas K.
1,5-Ring closure of 1- or 3-substituted hex-5-enyl radicals affords mainly cis-disubstituted cyclic products, whereas 2- or 4-substituted species give mainly trans-products; the significance of this stereoselectivity is demonstrated in the formation of the norbornane system from acyclic precursors.
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