Titanocene- and zirconocene-mediated cyclization of allyl propargyl ethers. Stereoselective synthesis of 3-methylenetetrahydrofurans

DOI: 10.1016/S0040-4039(96)02128-4

Source and publish data:

Tetrahedron Letters p. 9059 - 9062 (1996)

Update date:2022-08-10

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Authors:

Miura, Katsukiyo

Funatsu, Masashi

Saito, Hiroshi

Ito, Hajime

Hosomi, Akira

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Article abstract of DOI:10.1016/S0040-4039(96)02128-4

Low-valent titanium and zirconium reagents in situ prepared from metallocene dichlorides (Cp₂MCl₂: M = Ti, Zr) and magnesium powder activated by 1,2-dibromoethane smoothly reacted with allyl propargyl ethers to afford 3-methylenetetr

Full text of DOI:10.1016/S0040-4039(96)02128-4

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