Synthesis and Consecutive Double Alkylation Reactions of (2-Siloxyallyl)silanes as the Synthetic Equivalent of Acetone α,α'-Dianion

Article abstract of DOI:10.1021/jo00275a004

(2-Siloxyallyl)silanes as the synthetic equivalent of tandem acetone α,α'-dianion, readily prepared by quenching of the enolate of α-(trimethylsilyl)acetone with chlorosilanes or by 1,3 C->O Si shift of bis(organosilyl)acetone, react with various electrop