Organosilyl Iron Carbonyl Complexes: Synthesis and Reactivity towards Alkynes and Nitriles

DOI: 10.1039/c39800000278

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 278 - 279 (1980)

Update date:2022-08-11

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Authors:

Corriu, Robert J. P.

Moreau, Joel J. E.

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Article abstract of DOI:10.1039/c39800000278

The di-iron complex 2, readily obtained from Fe(CO)5 and Ph2SiH2 under photochemical conditions, react with the alkynes to yield the new mono- and bi-metallic complexes (R = Ph, Me, or Et) and ; the former complexes convert nitriles into aldehydes via disylilated enamines.

Full text of DOI:10.1039/c39800000278

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