910650-82-7

Basic information

• Product Name: Fluorobis(phenylsulfonyl)methane
• Synonyms: Fluorobis(phenylsulfonyl)methane
• CAS NO: 910650-82-7
• Molecular Formula: C₁₃H₁₁FO₄S₂
• Molecular Weight: 314
• Mol File: 910650-82-7.mol
• Article Data: 14

Chemical Properties

• Melting Point: 114-115℃ (hexane )
• Boiling Point: 539.6±50.0 °C(Predicted)
• Appearance: /
• Density: 1.408±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Fluorobis(phenylsulfonyl)methane(CAS DataBase Reference)
• NIST Chemistry Reference: Fluorobis(phenylsulfonyl)methane(910650-82-7)
• EPA Substance Registry System: Fluorobis(phenylsulfonyl)methane(910650-82-7)

Safety Data

• Safety Statements: 24/25
• Hazardous Substances Data: 910650-82-7(Hazardous Substances Data)

Usage

Uses

(Fluoromethylenedisulfonyl)dibenzene is a nucleophilic fluoromethylating agent.

Upstream product

• 3406-02-8 bis(phenylsulfonyl)methane 
• 60839-94-3 2-fluoro-methylthiobenzene 
• 7205-91-6 phenylthiomethyl chloride 
• 100-68-5 methyl-phenyl-thioether 
• 98-09-9 benzenesulfonyl chloride 
• 20808-12-2 fluoromethyl phenyl sulfone 
• 368-43-4 phenylsulfonyl fluoride 
• 1151549-59-5 [fluoro(phenylsulfinyl)methylsulfonyl]benzene 
• 1061868-34-5 α-fluoro-α-phenylthio-α-phenylsulfonylmethane 

Downstream Products

• 911136-06-6 Acetic acid (1R,4S)-4-(bis-benzenesulfonyl-fluoro-methyl)-cyclopent-2-enyl ester 
• 1352637-35-4 methyl 3-(3-chlorophenyl)-4-fluoro-2-methylene-4,4-bis(phenylsulfonyl)butanoate 
• 1352637-36-5 methyl 3-(4-chlorophenyl)-4-fluoro-2-methylene-4,4-bis(phenylsulfonyl)butanoate 
• 1322592-09-5 methyl 3-(2-chlorophenyl)-4-fluoro-2-methylene-4,4-bis(phenylsulfonyl)butanoate 
• 1352637-39-8 methyl 3-(3-methylphenyl)-4-fluoro-2-methylene-4,4-bis(phenylsulfonyl)butanoate 
• 1322592-12-0 methyl 3-(4-methylphenyl)-4-fluoro-2-methylene-4,4-bis(phenylsulfonyl)butanoate 
• 1352637-37-6 methyl 3-(2-bromophenyl)-4-fluoro-2-methylene-4,4-bis(phenylsulfonyl)butanoate 
• 1352637-40-1 methyl 3-(3-methoxylphenyl)-4-fluoro-2-methylene-4,4-bis(phenylsulfonyl)butanoate 
• 1322592-11-9 methyl 3-(4-bromophenyl)-4-fluoro-2-methylene-4,4-bis(phenylsulfonyl)butanoate 
• 1352637-43-4 methyl 4-fluoro-2-methylene-3-(naphthalen-2-yl)-4,4-bis(phenylsulfonyl)butanoate 

Relevant articles and documents

Mechanochemical electrophilic fluorination of liquid beta-ketoesters

An improved substrate scope for the mechanochemical electrophilic fluorination of dicarbonyls is reported. The applicable substrates have now been broadened to include liquid β-ketoesters. Key to this capability is the inclusion of a grinding auxiliary (NaCl) to improve mass transfer and prevent pasting or gumming of the reaction mixture. Notably, the use of a small amount of acetonitrile is critical to increasing the rate of reaction, ensuring complete consumption of starting materials during the short reaction times as well as improving the selectivity for the monofluorinated product in the mill.

A synthetic fluorine-containing acyclonucleosides analogues method

The invention discloses a method for synthesizing fluorine-containing noncyclic nucleoside analog. The reaction equation is shown in the specification, wherein R1 is selected from one of methoxyl, ethyoxyl, piperidine, morpholine, dimethylamino and phenme

Preparation of α-Fluorobis(phenylsulfonyl)methane (FBSM)

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