Journal of the Chemical Society - Faraday Transactions p. 603 - 607 (1990)
Update date:2022-08-24
Topics:
Vinckier, Chris
Corthouts, Johan
Jaegere, Stephan De
The sublimation of the copper halides CuCl or CuCl2 in microwave-induced plasma afterglows results in the chemiluminescence of CuCl at 300 K.In O2-He afterglows the A, B, C, D, E and F trasitions up from V'= 3 are observed, while H2-He afterglows are much less effective, showing only A and B transitions.In addition, a weak chemiluminescence of CuO is detected in O2-He afterglows.Various chemiluminescence mechanisms are discussed, from which it appears that the termolecular recombination of hydrogen or oxygen atoms, with CuCl or CuO acting as a third body, is the most plausible chemiexcitation mechanism.
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