Tetrahedron Letters p. 367 - 370 (1989)
Update date:2022-08-11
Topics:
Takeda, Hideo
Tachinami, Takeshi
Aburatani, Masakazu
Takahashi, Hisashi
Morimoto, Toshiaki
Achiwa, Kazuo
The neutral chiral N-substituted CPM-rhodium complexes were found to be efficient catalysts for asymmetric hydrogenation of 3'-benzyloxy-2-(N-benzyl-N-methyl)aminoacetophenone hydrochloride.A practical asymmetric synthesis of (R)-(-)-phenylephrine hydrochloride catalyzed by newly synthesized (2R,4R)-MCCPM-rhodium complex has been achieved.
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