A new preparative method, characterization, and reactivity of disulphide dication salts of cyclic bis-sulphides: R2S-SR2· 2CF3SO3-

DOI: 10.1039/C39870000930

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Journal of the Chemical Society. Chemical communications p. 930 - 931 (1987)

Update date:2022-08-12

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Authors:

Fujihara, Hisashi

Akaishi, Ryouichi

Furukawa, Naomichi

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Article abstract of DOI:10.1039/C39870000930

The reaction of 1,5-dithiacyclo-octane 1-oxide with trifluoromethanesulphonic anhydride affords the corresponding disulphide dication as a stable crystalline salt which serves as an oxidizing agent in the oxidation of 1,2-diphenylhydrazine; the disulphide dication of 1,4-dithiane has also been isolated.

Full text of DOI:10.1039/C39870000930

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