Sulfur, normally a poison, strongly promotes chemoselective catalytic hydrogenation: Stereochemistry and reactivity of crotonaldehyde on clean and S-modified Cu(111)

DOI: 10.1039/b517154g

Source and publish data:

Chemical Communications p. 1283 - 1285 (2006)

Update date:2022-08-25

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Authors:

Chiu, May E.

Kyriakou, Georgios

Williams, Federico J.

Watson, David J.

Tikhov, Mintcho S.

Lambert, Richard M.

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Article abstract of DOI:10.1039/b517154g

Sulfur adatoms strongly activate the otherwise inert Cu(111) surface towards chemoselective hydrogenation of crotonaldehyde by electronically perturbing and strongly tilting the reactant. The Royal Society of Chemistry 2006.

Full text of DOI:10.1039/b517154g

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