Journal of the Chemical Society - Faraday Transactions p. 3803 - 3807 (1990)
Update date:2022-08-30
Topics:
Burch, Robert
Tsang, Shik Chi
Swarnakar, Ramdayal
Detailed kinetic measurements have been made for the methane coupling reaction over a reducible and a irreducible oxide catalyst for a range of temperatures and methane and oxygen partial pressures.The results show a correlation with methane partial pressure which suggests that the reaction is close to second order with respect to methane.The results are analysed in terms of Rideal-redox and Langmuir-Hinshelwood models, and it is shown that the results can be explained by a Langmuir-Hinshelwood model in which the rate determining step is assumed to be surface coupling of adsorbed methyl moieties.However, the existence of a kinetic isotope effect in the formation of ethane from methane is not consistent with the model.An alternative model is presented in which the regeneration of the active centres on the surface of the catalyst is included in the kinetic analysis.This model correctly predicts a "pseudo"-second-order reaction with respect to the methane partial pressure, but is also consistent with the observed kinetic isotope effect.
View MoreBeijing Century Richap Chemistry Co.,Ltd
Contact:+86- 010-64455497
Address:Guannan County, Lianyungang City, Jiangsu Province, China
Contact:18698110882
Address:1303 No2 building,LuoMa Garden,YongAn Road,Hexi District,Tianjin city
Anhui New Star Pharmaceutical Development Co., Ltd
Contact:013956922763
Address:Floor 3, F9A, F Workshop, No.110 Kexue Road, High-Tech Development Zone, Hefei, Anhui ,China
Contact:886 2 2541 0022
Address:8 Fl., No. 11, Sec. 1, Chung Shan North Rd., Taipei, Taiwan R.O.C.
Yixing Bluwat Chemicals Co., Ltd.
Contact:+86 510 87821568
Address:Yongan Road, Yixing Chemical Industrial Park, Yixing, Jiangsu, China
Doi:10.1021/acs.inorgchem.8b00240
(2018)Doi:10.1016/0584-8539(76)80146-8
(1976)Doi:10.1016/j.bmc.2018.11.002
(2018)Doi:10.1039/C19670000102
(1967)Doi:10.1007/s11164-021-04464-0
(2021)Doi:10.1021/acs.joc.9b02187
(2019)