Regioreversed Addition of Crotylmagnesium Chloride to Carbonyl Compounds in the Presence of AlCl3

DOI: 10.1021/jo00157a046

Source and publish data:

Journal of Organic Chemistry p. 1564 - 1565 (1983)

Update date:2022-08-11

Topics:

Authors:

Yamamoto, Yoshinori

Maruyama, Kazuhiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00157a046

The reaction of carbonyl compounds with crotylmagnesium chloride in the presence of AlCl3 at -78 deg C gives predominantly products in which the allylic group is attached at the less substituted position (α-adduct).

Full text of DOI:10.1021/jo00157a046

Products guided by the article

Product name:1-phenylpent-3-en-1-ol

Cas No:124004-57-5

R&D Labs maybe for 124004-57-5

Sanming Coffer Fine Chemical Industrial Co., Ltd

website:http://www.cofferxm.com/

Contact:+86-598-5853979

Address:Jin-sha Yuan Chuang-ye Park,Hi-Tech Development Zone,Sanming City P.R.China
JinTan Pingsheng Chemical Co.,Ltd

Contact:+86-519-82828200

Address:NO.11Danfengxilu Road,Jintan City,Jiangsu,China
Beijing Huikang Boyuan Chemical Tech Co.,LTD

Contact:+86-10-68862197

Address:No.7 Haiying Road,Science City,Fengtai District,Beijing,China
Zouping Fuhai Technology Development Co., Ltd.

Contact:+0532-86934525 18660293207

Address:jiuhu town industrial park Zouping County,bingzhou Provincejiuhu town industrial park
Improve Medical Technology(Nanxiong) Co., Ltd

Contact:86-751-3836997

Address:No.33, Pingan First Road, Fine Chemical Industry Base, Nanxiong City, Shaoguan, Guangdong, China

Relevant to this article

Doi:10.1021/ja00431a074
(1976)
Doi:10.1039/CT9048500523
(1904)
Total synthesis of (±)-Calanolide A

Doi:10.1080/00397919608003823
(1996)
Supramolecular assemblies from amphiphilic homopolymers: Testing the scope

Doi:10.1021/ja065213o
(2006)
Synthesis of tritium labelled (R) and (S)-3-aminoquinuclidine: A ubiquitous component of serotonin receptor ligands, part I

Doi:10.1002/(SICI)1099-1344(199601)38:1<41::AID-JLCR811>3.0.CO;2-N
(1996)
Asymmetric hetero Diels-Alder reaction using chiral cationic metallosalen complexes as catalysts

Doi:10.1016/S0040-4020(00)01048-6
(2001)

Article Doi