Catalytic and Asymmetric Epoxidation of Olefins with Iron Complexes of "Twin-Coronet" Porphyrins. A Mechanistic Insight into the Chiral Induction of Styrene Derivatives

DOI: 10.1021/ja00018a024

Source and publish data:

Journal of the American Chemical Society p. 6865 - 6872 (1991)

Update date:2022-08-11

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Authors:

Naruta, Yoshinori

Tani, Fumito

Ishihara, Nobuo

Maruyama, Kazuhiro

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Article abstract of DOI:10.1021/ja00018a024

As a cytochrome-P-450-modeling asymmetric-oxidation system we designed and synthesized novel chiral C₂-symmetric "twin-coronet" porphyrins, which have chiral biaryl auxiliaries (i.e. binaphthyl and bitetralin derivatives) linked by ethereal bon

Full text of DOI:10.1021/ja00018a024

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