Journal of the Chemical Society. Chemical communications p. 1483 - 1485 (1989)
Update date:2022-08-18
Topics:
Ashwell, Susan
Davies, Alwyn G.
Golding, Bernard T.
Hay-Motherwell, Robyn
Mwesigye-Kibende, Samson
Photolysis of di-t-butyl 1-bromomethylcyclopropane-1,2-dicarboxylate (1a) in cyclopropane containing triethylsilane and di-t-butyl peroxide gave the 4-methylenepent-2-yl-1,5-dioic acid radical (3c), which was also produced from treatment of (1a), its cis-isomer (2b), di-t-butyl-2-bromo-4-methyleneglutarate (3a), or di-t-butyl 2-bromomethyl-3-methylenesuccinate (4b), with triphenyltin hydride; these experiments support a mechanism via proteinbound free radicals for the B12-dependent enzyme α-methyleneglutarate mutase.
View MoreContact:0550-7041128 0550-7090578
Address:Wangdian Street,Xinjie Town
Contact:+86-29-88710656
Address:South Tai bai Road, High Tech Development Zone, Xi'an China
Xinji City Taida Sinopec Co., Ltd.
Contact:0086-311-85341278
Address:No.6, Nanhua Road,Xinji City Road,Hebei Province,China
VanderArk International Limited
Contact:86-10-82437576
Address:Qing He
Zhejiang Allied Chemical Co.,Ltd
Contact:18967038207
Address:Area A-30, High-tech Industrial Park, Quzhou, Zhejiang, China.
Doi:10.1002/chem.200600899
(2007)Doi:10.1021/jo9823745
(1999)Doi:10.1039/c8dt02308e
(2018)Doi:10.1524/zpch.2001.215.3.283
(2001)Doi:10.1021/acs.jpca.7b07990
(2017)Doi:10.1021/ja00794a062
(1973)
