Asymmetric hydrolysis of α-alkylated cyclohexanone enol acetates by the cultured cells of Marchantia polymorpha

DOI: 10.1016/S0957-4166(97)00329-7

Source and publish data:

Tetrahedron Asymmetry p. 2671 - 2673 (1997)

Update date:2022-08-11

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Authors:

Hirata, Toshifumi

Shimoda, Kei

Ohba, Daisuke

Furuya, Noriko

Izumi, Shunsuke

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Article abstract of DOI:10.1016/S0957-4166(97)00329-7

The cultured suspension cells of Marchantia polymorpha hydrolyzed cyclohexanone enol acetates with 2-alkyl groups to afford optically active ketones. The stereoselectivity of the protonation of the enol intermediate was reversed when the chain length of alkyl substituents was increased.

Full text of DOI:10.1016/S0957-4166(97)00329-7

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