Tetrahedron Asymmetry p. 2671 - 2673 (1997)
Update date:2022-08-11
Topics:
Hirata, Toshifumi
Shimoda, Kei
Ohba, Daisuke
Furuya, Noriko
Izumi, Shunsuke
The cultured suspension cells of Marchantia polymorpha hydrolyzed cyclohexanone enol acetates with 2-alkyl groups to afford optically active ketones. The stereoselectivity of the protonation of the enol intermediate was reversed when the chain length of alkyl substituents was increased.
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Doi:10.1021/acs.orglett.8b01921
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(1997)Doi:10.1016/j.ica.2015.01.033
(2015)