Journal of the Chemical Society, Dalton Transactions p. 1405 - 1409 (1990)
Update date:2022-08-11
Topics:
Constable, Edwin C.
Ward, Michael D.
The oligopyridine 6',6''-bis(2-pyridyl)2,2':4,4'':2'',2'''-quaterpyridine (L) has been prepared.It may be regarded as a 'back-to-back' analogue of the well known 2,2':6',2''-terpyridine (terpy).Complexes with ruthenium(II) and palladium(II) have been characterised.The diruthenium(II) complex cation <(terpy)RuLRu(terpy)>4+ has been shown to exhibit no Ru-Ru interactions, and behaves as two non-interacting Ru(terpy)2 units.
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