Journal of the Chemical Society, Dalton Transactions p. 1081 - 1088 (1992)
Update date:2022-08-30
Topics:
Carofiglio, Tommaso
Floriani, Carlo
Sgamellotti, Antonio
Rosi, Marzio
Chiesi-Villa, Angiola
Rizzoli, Corrado
High-yield syntheses (<*>90percent) of the monocyclopentadienyloxochloro complexes <(TiLCl2)2)(μ-O)> 2, <(TiLCl)4(μ-O)4>3, <(TiL)4(μ-O)6> 4 and <(TiLCl)3(μ-O)3> 5 have been achieved by hydrolysis of the precursors a = 16.724(2), b = 8.958(1), c = 22.871(2) Angstroem, β = 91.73(1) deg, Z = 4 and R = 0.065 for 3159 independent observed reflections; 9. monoclinic, space group Cc, a = 24.527(2), b= 12.520(2), c= 18.931(2) Angstroem, β=115.46(2) deg, Z = 4 and R = 0.060 for 3088 independent observed reflections.The electronic configurations of complexes 2-5 have been calculated by extended Hueckel molecular orbital calculations.
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